Facile synthesis of spinel nickel-manganese cobaltite nanoparticles with high rate capability and excellent cycling performance for supercapacitor electrodes

초록

Nickel- and manganese-based spinel compounds have emerged as important candidates for electrochemical energy storage. In this study, a spinel nickel-manganese cobaltite (s-NMC) material was synthesized by facile hydrothermal/calcination route and the material exhibited remarkable pseudocapacitive behavior performance. The synthesized s-NMC material had a specific capacitance of 418.3 F g(-1) at a scan rate of 10 mV s(-1) (216.2 F g(-1) at a current density of 1 A g(-1)) and retained 95% of its specific capacitance after 5000 charge-discharge cycles at a current density of 2 A g(-1). These excellent electrochemical properties are attributed to the simultaneous presence of three transition metals in the s-NMC material. The asymmetric supercapacitor device using s-NMC delivered a maximum specific energy density of 16.58 Wh kg(-1) at a specific power density of 825 W kg(-1) and maintains of similar to 97% specific capacitance after 2000 cycles at a current density of 2 A g(-1). This study highlights that the diversification of transition metals in spinel-based metal oxides is an effective approach to enhance the electrochemical performances in resulting compound materials. [GRAPHICS] .

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