Air oxidation-induced single-crystal-to-single-crystal transformation of mixed-valence tetranuclear Fe(II)-Fe(III) complexes

Shin, Jong Won; Ullah, Ihsan; Tokunaga, Ryuya; Hayami, Shinya; Min, Kil Sik

doi:10.1039/d2dt02551e

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Air oxidation-induced single-crystal-to-single-crystal transformation of mixed-valence tetranuclear Fe(II)-Fe(III) complexes

Shin, Jong Won;
Ullah, Ihsan;
Tokunaga, Ryuya;
Hayami, Shinya;
Min, Kil Sik

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초록

A mixed valence tetranuclear iron complex [(Hpmide)Fe-II(NCSe)(2)Fe-III(pmide)](2)center dot 5CH(3)OH (1) underwent oxidation and ligand exchange in the solid state (H(2)pmide = N-(2-pyridylmethyl)iminodiethanol). Upon air oxidation, 1 was converted into [(pmide)Fe-III(NCSe)Fe-III(pmide)](2)(NCSe)(2)center dot 2H(2)O (2), which was accompanied by deprotonation and ligand exchange through a single crystal-to-single-crystal transformation.

키워드

METAL-ORGANIC FRAMEWORK; PI-PI INTERACTION; DINUCLEAR IRON(III); TEMPERATURE; PARAMETERS; STATES

제목: Air oxidation-induced single-crystal-to-single-crystal transformation of mixed-valence tetranuclear Fe(II)-Fe(III) complexes

저자: Shin, Jong Won; Ullah, Ihsan; Tokunaga, Ryuya; Hayami, Shinya; Min, Kil Sik

DOI: 10.1039/d2dt02551e

발행일: 2022-10-04

유형: Article

저널명: Dalton Transactions

권: 51

호: 38

페이지: 14429 ~ 14433

언어: ENG

출판사: ROYAL SOC CHEMISTRY

발행국가: 영국

분량: 5 페이지

ISSN: E 1477-9234
P 1477-9226