A Novel Synthesized 1D Nanobelt-like Cobalt Phosphate Electrode Material for Excellent Supercapacitor Applications

초록

In the present report, we synthesized highly porous 1D nanobelt-like cobalt phosphate (Co2P2O7) materials using a hydrothermal method for supercapacitor (SC) applications. The physicochemical and electrochemical properties of the synthesized 1D nanobelt-like Co2P2O7 were investigated using X-ray diffraction (XRD), X-ray photoelectron (XPS) spectroscopy, and scanning electron microscopy (SEM). The surface morphology results indicated that the deposition temperatures affected the growth of the 1D nanobelts. The SEM revealed a significant change in morphological results of Co2P2O7 material prepared at 150 degrees C deposition temperature. The 1D Co2P2O7 nanobelt-like nanostructures provided higher electrochemical properties, because the resulting empty space promotes faster ion transfer and improves cycling stability. Moreover, the electrochemical performance indicates that the 1D nanobelt-like Co2P2O7 electrode deposited at 150 degrees C deposition temperature shows the maximum specific capacitance (Cs). The Co2P2O7 electrode prepared at a deposition temperature 150 degrees C provided maximum Cs of 1766 F g(-1) at a lower scan rate of 5 mV s(-1) in a 1 M KOH electrolyte. In addition, an asymmetric hybrid Co2P2O7//AC supercapacitor device exhibited the highest Cs of 266 F g(-1), with an excellent energy density of 83.16 Wh kg(-1), and a power density of 9.35 kW kg(-1). Additionally, cycling stability results indicate that the 1D nanobelt-like Co2P2O7 material is a better option for the electrochemical energy storage application.

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