Enhancement of stimulated emission in Eu3+ activated oxyfluoroborotellurite glasses for reddish orange laser material

초록

Eu3+ activated oxyfluoroborotellurite glasses are enhancement stimulated emission by substitution of B<inf>2</inf>O<inf>3</inf> with NaF whereas concentration of Eu3+ are fixed at 1.00 mol%. The present glasses have been prepared by melt quenching method. Seven absorption bands of present glasses have been observed in UV–VIS and NIR regions which originated from ground 7F<inf>0</inf> and thermally populated 7F<inf>1</inf> states to excited states. The absorption transitions of 7F<inf>0</inf>→5L<inf>6</inf> and 7F<inf>0</inf>→7F<inf>6</inf> were more intense compared to all transitions. The substitution of B<inf>2</inf>O<inf>3</inf> with NaF has led to minor change absorption intensities. By stimulating with 395 nm, the emission spectra of present glasses exhibited four peaks which corresponding to 5D<inf>0</inf>→7F<inf>1,2,3,4</inf> transitions. The transition of 5D<inf>0</inf>→7F<inf>2</inf> showed the highest emission intensity. The substitution of B<inf>2</inf>O<inf>3</inf> with NaF can enhance emission intensity due to the reduction of hydroxyl group. While the highest emission intensity has been found to be 35 mol% of NaF concentration. The absorption and emission results have been calculated stimulated emission by using Judd-Ofelt (JO) theory. The stimulated emission is found to be 109.1 × 10–21 cm2. Including the branching ratio is higher than 0.50. In the frame of chromaticity color coordinate which the present glasses are fallen in the reddish orange region. The results indicate that Eu3+ activated oxyfluoroborotellurite glasses could be used potentially for reddish orange laser material. © 2023 Elsevier GmbH

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