Enhancing High-Rate Charge-Discharge Performance of Lithium-Sulfur Batteries Using Carbon Black Interlayer

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초록

In this study, the cathode was coated with Super P, a low-cost conductive carbon, to simplify the process and reduce cost. Electrodes with different sulfur ratios were assembled into cells to characterize their CV curves and impedances. The S0.6-sp cell shows a high discharge capacity of 600 mAh g(-1) at 2 C and 967 mAh g(-1) at 0.5 C. These values are 10% and 25% higher, respectively, compared to S0.53 cells with the same carbon-to-sulfur ratio. Afterward, the S0.6-sp cell was disassembled to observe the suppression of the shuttle effect by confirming the appearance of the separator. In addition, through SEM images, electrode structure collapse caused by the Li2S/Li2S2 layer was insignificant.

키워드

Lithium-sulfur batteries; Carbon black; Cathode coating; Interlayer; Electrochemical performances; LI-S BATTERY; POROUS CARBON; NANOMATERIALS; NANOTUBES; ELECTRODE; GRAPHENE; BARRIER; LAYER; HOST
제목
Enhancing High-Rate Charge-Discharge Performance of Lithium-Sulfur Batteries Using Carbon Black Interlayer
저자
Lee, Jae Bin; Min, Gyeonguk; Lim, Won-Gwang; Kang, Hyunchul; Shin, Kyuchul; Yoon, Songhun; Lee, Jinwoo; Joo, Jin
DOI
10.1007/s11814-024-00057-w
발행일
2024-03
유형
Article
저널명
Korean Journal of Chemical Engineering
권
41
호
4
페이지
1239 ~ 1248