β-like FeOOH Nanoswords Activated by Ni Foam and Encapsulated by rGO toward High Current Densities, Durability, and Efficient Oxygen Evolution

초록

As an alternative to the oxygen evolution reaction (OER) electrocatalyst developed by a complex bi- or multimetal ion with layered double hydroxide (LDH) structures, we design a simple, self-supported, and single-metal-ion OER electrocatalyst having lower overpotentials and high current densities in alkaline water electrolyzers. Here, beta-like FeOOH nanosword structures encapsulated by reduced graphene oxide (rGO) were cost-effectively synthesized on formable Ni foam substrates as an efficient and highly durable OER catalyst. It is revealed that the rGO uniformly covered the beta-like FeOOH nanoswords to form a porous network achieving a lower overpotential of only 210 mV at 10 mA cm(-2) with a stable operation for more than 40 h in alkali media. Moreover, a high current density of similar to 300 mA cm(-2) was achieved at less than 1.8 V. In-depth physical and electrochemical analysis indicated that the intrinsic charge transfer through activated Ni-foam, beta-like phase, and nanosword morphology was evidently beneficial for enhancing the OER activity of the bare FeOOH, and its encapsulation by rGO further improved the conductivity and long-life durability. Our integrated OER electrocatalyst developed by a simple method (repeated soaking and quenching process) will aid in scaling up beta-like FeOOH nanoswords for preparing uniform and large-area electrodes for industrial purposes.

키워드