Microwave-Assisted Synthesis of Reduced Graphene Oxide with Hollow Nanostructure for Application to Lithium-Ion Batteries

초록

In this study, reduced graphene oxide (RGO) with a hollow nanostructure was successfully synthesized by layer-by-layer self-assembly using electrostatic interactions and van der Waals forces between building blocks, and its lithium storage characteristics were investigated. After 800 cycles at a current density of 1 A/g, the microwave-irradiated RGO hollow spheres (MRGO-HS) maintained a capacity of 626 mA h/g. In addition, when the charge/discharge capacity was measured stepwise in the current density range of 0.1-2 A/g, the discharge capacity of the RGO rapidly decreased to 156 mA h/g even at the current density of 2 A/g, whereas MRGO-HS provided a capacity of 252 mA h/g. Even after the current density was restored at a current density of 0.1 A/g, the MRGO-HS capacity was maintained to be 827 mA h/g at the 100th cycle, which is close to the original reversible capacity. Thus, MRGO-HS provides a higher capacity and better rate capability than those of traditionally synthesized RGO.

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