Fabrication of Z-scheme Fe2O3/g-C3N4 nanocomposite with improved visible light induced photodegradation of pharmaceutical pollutants and photoelectrochemical water oxidation

초록

The photodegradation and photoelectrochemical performance of Fe2O3 catalyst is an encouraging visible-light induced catalyst owing to its less harmfulness, cheap and ecofriendly. However, owing to its quick charge carriers recombination rate and less lifespan of charge carriers obstructs its catalyst application. Therefore, it has been lately established that the construction of heterojunction with other semiconductor might be a possible method to improve its catalytic activity. Herein, a novel Z-scheme Fe2O3/g-C3N4 heterostructure catalyst has been synthesized by a simple hydrothermal technique and studied its photoelectrochemical and photodegradation activity. The addition of g-C3N4 greatly improves the light absorption ability light, reduced charge recombination rate and progress the charge transportation. The composite catalyst exhibited the superior photodegradation performance (97.8 %) of sulfamethoxazole antibiotic remedy within 30 min of visible light illumination. center dot OH and center dot O-2(-) radicals show a key role for dye degradation activity, and proposed a possible photodegradation charge carrier transfer mechanism based on a potential band structures of composite catalyst. Furthermore, the prepared catalysts are further used to examine the photoelectrochemical properties for hydrogen generation. The Fe2O3/g-C3N4 nanocomposite photoelectrode exhibited enriched photocurrent density (0.764 mA/cm(2)) than g-C3N4 (0.271 mA/cm(2)) and Fe2O3 (0.370 mA/cm(2)) photoelectrodes, which similar to 2.8 and similar to 2.1 folds greater photocurrent density than pure photoelectrodes. Electrochemical impedance spectroscopy analysis revealed that the composite electrode has minimal charge transfer resistance and greater electron transfer ability. Therefore, the current study presents a facile formation of Z-scheme catalyst and offers a sustainable method to eradicate water impurities and hydrogen generation by renewable solar energy.

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