Investigation of spectroscopic and photoluminescence properties of Erbium doped phosphate (P2O5-K2O3-Al2O3) glasses

초록

Erbium (Er) doped P2O5-K2O3-Al2O3:Er2O3 glasses (KPEr) with different contents of Er3+ ions were fabricated by famous melt-quenching technique. The fabricated samples were characterized by using physical, X-ray photoelectron spectroscopy (XPS), photoluminescence, absorption, and J-O analysis techniques. The XRF analyses were performed in order to know the change in elemental composition of fabricated glasses, while using the various concentrations of Er3+ ions. Three emission peaks were observed, two peaks in visible regions of 526 nm (H-2(11/2) -> I-4(15/2)) and 550 nm (S-4(3/2) -> I-4(15/2)) and one peak in near infrared (NIR) region of 1545 nm (I-4(13/2) -> I-4(15/2)). Nine peaks were observed in absorption spectra in the range of 390-1800 nm. The trend of JO parameters for the present KPEr6 glass sample is Omega(2) > Omega(4) > Omega(6). Higher values of stimulated emission cross-section sigma(emi)(lambda), full wave half maxima FWHM and (FWHM x sigma(emi) (lambda)), for KPEr6 indicate that the present glass has potential candidate to be used for broadband amplification in telecommunication. The McCumber theory is used to study absorption and emission cross-section for I-4(13/2) -> I-4(15/2) transition. The luminescence colors of these samples were almost entirely fall in the yellow green (Y-G) region (x = 0.33, y = 0.64) in the CIE 1931 diagram. The calculated CCT values for our prepared glasses were found to be 5554 K. The present study suggest that KPEr glass samples have potential candidate for broadband amplification in telecommunication, green LED and display devices. (C) 2021 Elsevier B.V. All rights reserved.

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